Asam Sulfat 60% (Sulfuric Acid 60% - H2SO4 60% - Asam Dilute - Dilute Acid)

Asam Sulfat 60% (Sulfuric Acid 60% - H2SO4 60% - Asam Dilute - Dilute Acid) Material Datasheet

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Identification of the substance/mixture

Product identifier

Product name : Sulfuric Acid 60

Chemical family : Inorganic Acid

Relevant identified uses of the substance or mixture and advised against Identified uses: Manufacture of fertilizers, manufacture of dyestuffs and pigments, manufacture of blowing Agent, manufacture of downstream of sulfate salts, bleaching earth, alkylation catalyst, electroplating baths, purification of petroleum.

2. Hazard Identification

Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008)

Corrosive to metals, Category 1, H290

Skin corrosion, Category 1A, H314

For the full text of the H-Statements mentioned in this section, see section 16.

Classification (67/548/EEC or 1999/45/EC)

C Corrosive R35

For the full text of the R-phrases mentioned in this section, see section 16.

Label elements

Labelling (REGULATION (EC) No.1272/2008)

Hazard pictograms

Signal word

Danger

Hazard statements

H290 May be corrosive to metals.

H314 Causes severe skin burns and eye damage.

Precautionary statements

Prevention

P280 Wear protective gloves/protective clothing/eye protection/face protection. Response

P301 + P330 + P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P309 + P310 IF exposed or if you feel unwell: Immediately call a POISON CENTER or doctor/physician.

Labelling (67/548/EEC or 1999/45/EC)

Symbols(s) C Corrosive

R-phrase(s) 35 Causes severe burns

S-phrase(s) 26-30-36/37/39-45 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

Never add water to this product. Wear suitable protective clothing, gloves and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

Other hazards

None known.

3. Composition / information on ingredients

Chemical nature Aqueous solution

Substance

Not applicable

Mixture

Hazardous components (REGULATION (EC) No 1272/2008)

Chemical Name (concentration)

CAS No. Registration number Classification

Sulphuric Acid (>60 %)

7664-93-9 *) Corrosive to metals, Category 1, H290 Skin corrosion, Category 1A, H314

*) A registration number is not available for this substance or its use are exempted from registration according to article 2 REACH Regulation (EC) No 1907/2006, tha annual tonnage does not require a registration or the registration is envisaged for a later registration deadline.

For the full text of the H-Statements mentioned in this section, see section 16. Hazardous components (1999/45/EC)

Chemical Name (concentration)

CAS No. Classification

Sulphuric Acid (>60 %)

7664-93-9 C; Corrosive; R35

For the full text of the R-phrases mentioned in this section, see section 16.

4. First aid measures

Description of first aid measures

General advice

First aider needs to protect himself

After inhalation : fresh air. Call in physician

After skin contact : wash off with plenty of water. Immediately remove contaminated clothing. Call a physician immediately.

After eye contact : rinse out with plenty of water. Immediatelly call in ophthalmologist. After swallowing: make victim drink water (two glasses at most), avoid vomiting (risk of perforation). Call a physician immediately. Do not attempt to neutralise

Most important symptoms and effects, both acute and delayed

Irritation and corrosion, Cough, Shortness of breath, Nausea, Vomiting, Diarrhoea, pain, Risk of blindness!.

Indication of immediate medical attention and special treatment needed No information available

5. Fire-fighting measures

Extinguishing media

Suitable extinguishing media: Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable extinguishing media: For this substance/mixture no limitations of extinguishing agents are given

Special hazards arising from the substance or mixture

No combustible.

Ambient fire may liberate hazardous vapours.

Fire may cause evolution of: Sulphur oxides.

Advice for firefighters

Special protective equipment for firefighters : stay in danger area only with self contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

6. Accidental release measures

Personal precaution, protective equipment and emergency procedures Advice for non emergency personnel: Do not breathe vapors, aerosols. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert.

Environmental precautions

Do not empty into drains

Methods and materials for containment and cleaning up

Take up with liquid-absorbent and neutralizing material (sand and lime). Clean up affected area.

Reference to the other sections

Indication about waste treatment see section 13.

7. Handling and storage

Precaution for safe handling

Advice on safe handling: Observe label precautions

Hygiene measures: Change contaminated clothing and immerse in water. Preventive skin protection Wash hands and face after working with substance.

Conditions for safe storage, including any incompatibilities

Storage conditions: Tightly closed.

Storage temperature: ambient or room temperature

Specific end uses.

Apart from the uses mentioned in section 1.2 no other specific uses are stipulated

8. Exposure controls/personal protection

Control parameters

Exposure controls

Engineering measures

Technical measures and appropriate working operations should be given priority over the use of personal protective equipment

Individual protection measures:

Protective clothing needs to be selected specifically for the workplace, depending on concentrations and quantities of the hazardous subtances handled. The chemical resistance of the protective equipment should be enquired at the respective supplier.

Eye / face protection

Tightly fitting safety goggles

Hand protection

Full contact :

Glove material : Viton (R)

Glove thickness : 0.70 mm

Break through time : > 480 min

splash contact :

Glove material : butyl-rubber

Glove thickness : 0.7 mm

Break through time : > 120 min

The protective gloves to be used must comply with the specifications of EC Directive 89/686/EEC and the related standard EN374.

Other protective equipment:

Acid-resistant protective clothing

Respiratory protection

Required when vapour/aerosols are generated.

Recommended filter type : Filter P2 (acc. To DIN 3181) for solid and liquid particles of harmful subsatances

Environmental exposure controls

Do not empty into drains.

9. Physical and chemical properties

Information on basic physical and chemical properties

Form: liquid

Colour: colorless to yellowish clear

Odour: odourless

Odour: Threshold not applicable

pH(20oC): strongly acid

Melting point: No information available.

Boiling point: No information available.

Flash point: No information available.

Evaporation rate: No information available.

Flammability (solid,gas): not applicable

Lower explosion limit: No information available.

Upper explosion limit: No information available.

Vapour pressure: No information available.

Relative vapour density: No information available.

Relative density: 1,52 g/cm3 at 20 °C

Water solubility at 20 °C: soluble, (caution! development of heat)

Partition coefficient: No information available.

Octanol/water

Decomposition temperature ca. 338 °C

Viscosity, dynamic: No information available.

Explosive properties: No information available.

Oxidizing properties: Oxidising potential

Other data

Corrosion: May be corrosive to metals.

10. Stability and reactivity

Reactivity

Has a corrosive effect

Strong oxidizing agent

Chemical stability

The product is chemically stable under standard ambient conditions (room temperature).

Possibility of hazardous reactions

A risk of explosion and/or of toxic gas formation exists with the following substances.

Violent reactions possible with:

Water, Alkali metals, alkali compounds, Ammonia, Aldehydes, acetonitrile, Alkaline earth metals, alkalines, Acids, alkaline earth compounds, Metals, metal alloys, Oxides of phosphorus, phosphorus, hydrides, halogen-halogen compounds, oxyhalogenic compounds, permanganates, nitrates, carbides, combustible substances, organic solvent, acetylidene, Nitriles, organic nitro compounds, anilines, Peroxides, picrates, nitrides, lithium silicade, iron(III) compounds, bromates, chlorates, Amines, perchlorates, hydrogen peroxide

Conditions to avoid

Strong heating

Incompatible materials

Animal/vegetable tissues, Metals

Contact with metals liberates hydrogen gas

Hazardous decomposition products

In the event of fire, see chapter 5.

11. Toxicological information

Information on toxicological effects

Mixture

Acute oral toxicity